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Studies of a series of novel rhenium(I) bipyridyl dyes for solar cells
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2005 (English)In: Chinese Chemical Letters, ISSN 1001-8417, E-ISSN 1878-5964, Vol. 16, no 5, 677-680 p.Article in journal (Refereed) Published
Abstract [en]

A series of novel rhenium(I) 2,2'-bipyridyl complexes [fac-Re(4,4'-di-COOEt-bpy)-(CO)(3)(Xpy)PF6], where bpy is 2,2'-bipyridine, py is pyridine and X is 3-methyl, 3-hydroxy, or 3-amino, were synthesized, their photophysical and electrochemical properties were studied. The Re(II/I) oxidation potentials decreased as the X group becomes more electron donating from H to 3-methyl, 3-hydroxy, or 3-amino, which might be a very convenient ways for adjusting the electron transfer driving force.

Place, publisher, year, edition, pages
2005. Vol. 16, no 5, 677-680 p.
Keyword [en]
rhenium(I) bipyridyl complex, redox potential, electron transfer driving force, excited-state properties, electron-transfer, complexes
Identifiers
URN: urn:nbn:se:kth:diva-14771ISI: 000229296800032OAI: oai:DiVA.org:kth-14771DiVA: diva2:332812
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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