Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Cation mobility and anion reorientation in lithium trifluoromethane sulfonate, LiCF3SO3
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.
2005 (English)In: Solid State Ionics, ISSN 0167-2738, E-ISSN 1872-7689, Vol. 176, no 15-16, 1449-1456 p.Article in journal (Refereed) Published
Abstract [en]

We present a detailed study of the dynamic processes present in the lithium ionic conductor lithium trifluoromethane sulfonate, LiCF3SO3. Using Li-7-, O-17- and F-19 solid state NMR line shape analysis and T-1-NMR, the anionic (CF3- and SO3-reorientation) and cationic dynamics (Li motion) could be studied separately. Whereas the CF3- and SO3 reorientations are active at ambient temperatures and not correlated to the cation motion, the NMR data indicate a strong correlation between the Li motion and the reorientation of the complete triflate anion.

Place, publisher, year, edition, pages
2005. Vol. 176, no 15-16, 1449-1456 p.
Keyword [en]
lithium trifluoromethane sulfonate, crystalline ionic conductors, solid state NMR, T-1-NMR, NMR line shape analysis, nuclear-magnetic-resonance, paddle-wheel mechanism, solid-state nmr, spin-lattice relaxation, polymer electrolytes, sodium orthophosphate, quadrupolar nuclei, percolation model, ionic conductors, beta-alumina
Identifiers
URN: urn:nbn:se:kth:diva-14861ISI: 000230094700014OAI: oai:DiVA.org:kth-14861DiVA: diva2:332902
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

Open Access in DiVA

No full text

Search in DiVA

By author/editor
Hildebrandt, Lars
By organisation
Applied Electrochemistry
In the same journal
Solid State Ionics

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 22 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf