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Synthesis and property of a chiral salen Mn(III) complex covalently linked to an Ru(II) tris(bipyridyl) photosensitizer
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2005 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 8, no 7, 606-609 p.Article in journal (Refereed) Published
Abstract [en]

A catalyst-photo sensitizer binuclear Mn(III)Ru(II) complex was prepared, in which the catalyst moiety of the Mn(III) unit with a chiral pyrrolidine salen ligand was covalently linked to a photosensitizer of the Ru(II) tris(bipyridyl) fragment. The electrochemical and photophysical properties of the Mn(III)Ru(II) complex were studied.

Place, publisher, year, edition, pages
2005. Vol. 8, no 7, 606-609 p.
Keyword [en]
manganese complex, ruthenium complex, heterobinuclear complex, chiral salen ligand, pyrrolidine, light-driven catalyst, intramolecular electron-transfer, ruthenium-manganese complexes, tris-bipyridine, epoxidation, state, stereochemistry, oxidation, ligands, model
URN: urn:nbn:se:kth:diva-14878DOI: 10.1016/j.inoche.2005.04.001ISI: 000230226500007ScopusID: 2-s2.0-20344393902OAI: diva2:332919
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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