Emission of possible odourous low molecular weight compounds in recycled biofibre/polypropylene composites monitored by head-space SPME-GC-MS
2005 (English)In: Polymer degradation and stability, ISSN 0141-3910, E-ISSN 1873-2321, Vol. 90, no 3, 555-562 p.Article in journal (Refereed) Published
A disadvantage of the use of natural fibres to reinforce polypropylene is their poor thermal stability, which results in their degradation at processing temperatures of the composites. As a result of this, there is a formation of low molecular weight compounds that are responsible for undesirable odours. Head-space-solid phase microextraction (HS-SPME) was used as a sample preparation technique and gas chromatography-mass spectrometry (GC-MS) was used to identify the low molecular weight compounds in natural polypropylene/polypropylene composites after simulating degradation. Among the compounds found in the samples, there are fragments of PP chains as heptadecane, compounds from antioxidants such as 2,4-bis(1,1-dimethylethyl)-phenol, and p-tert-butylphenol, and compounds from biofibres ageing, such as ethylparaben and vanillin. Numerous carboxylic acids were also identified, being these most probably the source of the undesirable odours.
Place, publisher, year, edition, pages
2005. Vol. 90, no 3, 555-562 p.
solid phase microextraction, polypropylene/cellulose composites, thermal degradation, solid-phase microextraction, chromatography-mass-spectrometry, volatile organic-compounds, low-density polyethylene, lignin model compounds, thermal-decomposition, packaging materials, identification, polypropylene, pyrolysis
IdentifiersURN: urn:nbn:se:kth:diva-15144DOI: 10.1016/j.polymdegradstab.2005.03.009ISI: 000232895000019ScopusID: 2-s2.0-25644439159OAI: oai:DiVA.org:kth-15144DiVA: diva2:333185
QC 201005252010-08-052010-08-052010-10-11Bibliographically approved