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An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydirogenases
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2006 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 3, 305-307 p.Article in journal (Refereed) Published
Abstract [en]

Protonation of [{(mu-SCH2)(2)N(C6H4-p-NO2)}{Fe(CO)(2)(PMe3)}(2)] in the presence of 4 equiv. of HOTf afforded two species, a mu-hydride diiron complex, the molecular structure of which was crystallographically characterized, and a p-S-protonated species, which was readily deprotonated in the presence of pyridine.

Place, publisher, year, edition, pages
2006. no 3, 305-307 p.
Keyword [en]
density-functional calculations, model complexes, hydrogen evolution, bridging ligand, iron, mimics, activation, dihydrogen, mechanism, h-2
URN: urn:nbn:se:kth:diva-15404DOI: 10.1039/b513270cISI: 000235034700035ScopusID: 2-s2.0-33645461565OAI: diva2:333445
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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