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The bromination mechanism of 1-aminoanthraquinone-2,4-disulfonic acid in sulfuric acid
2006 (English)In: Dyes and pigments, ISSN 0143-7208, E-ISSN 1873-3743, Vol. 71, no 3, 231-235 p.Article in journal (Refereed) Published
Abstract [en]

I-Amino-4-bromoanthraquinotie-2-sulfoiiic acid (bromoamine acid) is an important intermediate for dyes. 1-Aminoanthraquinone2,4-disulfonic acid is the major impurity when 1-aminoanthraquinone is sulfonated in oleum to synthesize bromoamine acid. The mechanism of bromination of 1-aminoanthraquinone-2,4-disulfonic acid in sulfuric acid has been studied. It is proved that I-aminoanthraquinone-2,4-disulfonic acid undergoes de-sulfonation first to form 1-aminoanthraquinoine-2-sulfonic acid, and then bromination to form bromoamine acid. Based on this mechanism, a new optimal process for the synthesis of bromoamine acid is developed. In this way, bromoamine acid is afforded in high yield and good quality.

Place, publisher, year, edition, pages
2006. Vol. 71, no 3, 231-235 p.
Keyword [en]
bromoamine acid, de-sulfonation, 1-aminoantraquinone-2,4-disulfonic acid
Identifiers
URN: urn:nbn:se:kth:diva-15409ISI: 000235092300011OAI: oai:DiVA.org:kth-15409DiVA: diva2:333450
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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