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Kinetics studies of hydrogen reduction of Cu2O
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Materials Process Science.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Materials Process Science.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering, Materials Process Science.
2006 (English)In: Zeitschrift für Metallkunde, ISSN 0044-3093, Vol. 97, no 1, 72-78 p.Article in journal (Refereed) Published
Abstract [en]

In present work, reduction kinetics Of Cu2O by hydrogen gas was studied by thermogravimetric analyses (TGA). The TGA experiments were carried out both isothermally and non-isothermally on shallow powder beds. It was established that additions of Ni or NiO did not have any serious effect on the kinetics of reduction of Cu2O. The composition and microstructures of the reaction products were analyzed after each experiment by X-ray diffraction (XRD) as well as by scanning electron microscopy (SEM). The activation energy for the reaction was evaluated from isothermal as well as non-isothermal reduction experiments and was found to be in good agreement. The impact of the stability of the oxide on the activation energy for hydrogen reduction is also discussed.

Place, publisher, year, edition, pages
2006. Vol. 97, no 1, 72-78 p.
Keyword [en]
copper oxide, hydrogen reduction, kinetics, activation energy, cuo, oxides, powder, gas, tungstate
National Category
Materials Engineering
Identifiers
URN: urn:nbn:se:kth:diva-15460ISI: 000235609500012Scopus ID: 2-s2.0-32644471395OAI: oai:DiVA.org:kth-15460DiVA: diva2:333501
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved
In thesis
1. Synthesis of nano sized Cu and Cu-W alloy by hydrogen reduction
Open this publication in new window or tab >>Synthesis of nano sized Cu and Cu-W alloy by hydrogen reduction
2005 (English)Licentiate thesis, comprehensive summary (Other scientific)
Abstract [en]

The major part of the present work, deals with the reduction kinetics of Cu2O powder and a Cu2O-WO3 powder mixture by hydrogen gas, studied by ThermoGravimetric Analysis (TGA). The reduction experiments were carried out both isothermally and non-isothermally on thin powder beds over different temperature intervals. During the experiments, the reductant gas flow rate was kept just above the starvation rate for the reaction to ensure that chemical reaction was the rate-controlling step. The activation energy for the reactions was evaluated from isothermal as well as non-isothermal reduction experiments.

In the case of the reduction of Cu2O, the impact of the stability of the copper oxide on the activation energy for hydrogen reduction under identical experimental conditions is discussed. A closer investigation of additions of Ni or NiO to Cu2O did not have a perceptible effect on the kinetics of reduction.

In the case of the reduction of the Cu2O-WO3 mixture, the reaction mechanism was found to be affected in the temperature range 923-973 K, which is attributed to the reaction/transformation in the starting oxide mixture. At lower temperatures, Cu2O was found to be preferentially reduced in the early stages, followed by the reduction of the tungsten oxide. At higher temperatures, the reduction kinetics was strongly affected by the formation of a complex oxide from the starting materials. It was found that the Cu2O-WO3 mixture underwent a reaction/transformation which could explain the observed kinetic behavior.

The composition and microstructures of both the starting material and the reaction products were analyzed by X-ray diffraction (XRD) as well as by microprobe analysis. vi Kinetic studies of reduction indicated that, the mechanism changes significantly at 923 K and the product formed had unusual properties. The structural studies performed by XRD indicated that, at 923 K, Cu dissolved in W forming a metastable solid solution, in amorphous/nanocrystalline state. The samples produced at higher as well as lower temperatures, on the other hand, showed the presence two phases, pure W and pure Cu. The SEM results were in conformity with the XRD analysis and confirmed the formation of W/Cu alloy. TEM analysis results confirmed the above observations and showed that the particle sizes was about 20 nm.

The structure of the W/Cu alloy produced in the present work was compared with those for pure copper produced from Cu2O produced by hydrogen reduction under similar conditions. It indicated that the presence of W hinders the coalescence of Cu particles and the alloy retains its nano-grain structure. The present results open up an interesting process route towards the production of intermetallic phases and composite materials under optimized conditions.

Place, publisher, year, edition, pages
Stockholm: KTH, 2005. x, 36 p.
Keyword
hydrogen reduction, kinetics, activation energy, copper oxide, copper tungsten composite, alloy powder, manostructure
National Category
Other Materials Engineering
Identifiers
urn:nbn:se:kth:diva-353 (URN)
Presentation
2005-06-02, Sal B2, Brinellvägen 23, Stockholm, 10:00
Supervisors
Note
QC 20101222Available from: 2005-08-01 Created: 2005-08-01 Last updated: 2010-12-22Bibliographically approved

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