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A furan-containing diiron azadithiolate hexacarbonyl complex with unusual lower catalytic proton reduction potential
2006 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 9, no 3, p. 290-292Article in journal (Refereed) Published
Abstract [en]

A new biomimetic model of the active site of Fe-only hydrogenase [{(mu-SCH2)(2)N(2-C4H3O)} Fe-2(CO)(6)] (6) was synthesized and characterized by IR, H-1, C-13 NMR spectroscopy. The butterfly based core structure was also confirmed by X-ray diffraction. The electrochemistry data indicated that the reductive potential at -1.13 V versus Fc/Fc(+) by HClO4 is the lowest of that reported.

Place, publisher, year, edition, pages
2006. Vol. 9, no 3, p. 290-292
Keyword [en]
hydrogenases, furan, diiron azadithiolate, proton reduction potential, fe-only hydrogenases, active-site, iron hydrogenase, desulfovibrio-desulfuricans, chemistry, models, coordination
Identifiers
URN: urn:nbn:se:kth:diva-15496DOI: 10.1016/j.inoche.2005.11.022ISI: 000235814300010Scopus ID: 2-s2.0-33144469822OAI: oai:DiVA.org:kth-15496DiVA, id: diva2:333537
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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