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Chiral, enantiopure aluminum(III) and titanium(IV) azatranes
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2006 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 5, 1032-1040 p.Article in journal (Refereed) Published
Abstract [en]

Al-III and Ti-IV complexes of C-3-symmetric tetradentate trisamidoamme ligands with trigonal bipyramidal coordination geometry, containing chlorine or dialkylamido groups, or with a free coordination site in the apical position, have been synthesised by salt metathesis and amine elimination. Products with threefold symmetry were generally obtained for tetravalent titanium, whereas for the aluminium complexes either asymmetric structures with two of the three podand arms taking part in coordination to the metal or symmetric arrangements possessing the full threefold symmetry were formed depending on the steric properties of the ligands.

Place, publisher, year, edition, pages
2006. no 5, 1032-1040 p.
Keyword [en]
aluminum, chirality, N ligands, titanium, tripodal ligands, tripodal amido complexes, early transition-metals, direct alpha-arylation, aryl chlorides, triamidoamine ligands, crystal-structures, structural-characterization, coordination chemistry, group-13 azatranes, tungsten complexes
Identifiers
URN: urn:nbn:se:kth:diva-15533DOI: 10.1002/ejic.200500657ISI: 000236135500016Scopus ID: 2-s2.0-33644993215OAI: oai:DiVA.org:kth-15533DiVA: diva2:333574
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Moberg, Christina

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