Change search
ReferencesLink to record
Permanent link

Direct link
Chiral, enantiopure aluminum(III) and titanium(IV) azatranes
Show others and affiliations
2006 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 5, 1032-1040 p.Article in journal (Refereed) Published
Abstract [en]

Al-III and Ti-IV complexes of C-3-symmetric tetradentate trisamidoamme ligands with trigonal bipyramidal coordination geometry, containing chlorine or dialkylamido groups, or with a free coordination site in the apical position, have been synthesised by salt metathesis and amine elimination. Products with threefold symmetry were generally obtained for tetravalent titanium, whereas for the aluminium complexes either asymmetric structures with two of the three podand arms taking part in coordination to the metal or symmetric arrangements possessing the full threefold symmetry were formed depending on the steric properties of the ligands.

Place, publisher, year, edition, pages
2006. no 5, 1032-1040 p.
Keyword [en]
aluminum, chirality, N ligands, titanium, tripodal ligands, tripodal amido complexes, early transition-metals, direct alpha-arylation, aryl chlorides, triamidoamine ligands, crystal-structures, structural-characterization, coordination chemistry, group-13 azatranes, tungsten complexes
URN: urn:nbn:se:kth:diva-15533DOI: 10.1002/ejic.200500657ISI: 000236135500016ScopusID: 2-s2.0-33644993215OAI: diva2:333574
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Moberg, Christina
By organisation
Organic Chemistry
In the same journal
European Journal of Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 20 hits
ReferencesLink to record
Permanent link

Direct link