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A novel ruthenium(II) tris(bipyridine)-zinc porphyrin-rhenium carbonyl triad: synthesis and optical properties
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2006 (English)In: Tetrahedron, ISSN 0040-4020, E-ISSN 1464-5416, Vol. 62, no 15, 3674-3680 p.Article in journal (Refereed) Published
Abstract [en]

A novel ruthenium(II) tris(bipyridine)-zinc porphyrin-rhenium carbonyl triads and its free base porphyrin derivative were synthesized and characterized by H-1, C-13 NMR, UV-vis, mass-spectrometry and elemental analysis. The redox potentials of the two Compounds were measured and compared to their corresponding reference complexes. The fluorescence and transient absorption spectra of the two complexes revealed the features of two different pathways for possible photoinduced intramolectular electron transfer or energy transfer in the triads.

Place, publisher, year, edition, pages
2006. Vol. 62, no 15, 3674-3680 p.
Keyword [en]
porphyrin, ruthenium, rhenium, photophysics, electron transfer, energy transfer, electron-transfer, energy-transfer, charge separation, excited-states, complexes, behavior, design, ligand, arrays, dyads
Identifiers
URN: urn:nbn:se:kth:diva-15565DOI: 10.1016/j.tet.2006.01.072ISI: 000236437400021Scopus ID: 2-s2.0-33644936214OAI: oai:DiVA.org:kth-15565DiVA: diva2:333606
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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