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(R)-1-Phenylethanaminium-(S,S)-2,3-dibromosuccinate-(R,R)-2,3-dibromosuccinic acid water (2/1/1/2)
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2006 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 62, O1281-O1283 p.Article in journal (Refereed) Published
Abstract [en]

From an aqueous solution of racemic 2,3-dibromosuccinic acid and (R)-1-phenylethanamine, crystals of the title compound, C8H12N+ .0.5C(4)H(2)Br(2)O(4)(2-) .0.5C(4)H(4)Br(2)O(4)(.)H(2)O, were obtained in almost quantitative yield. The structure contains both enantiomers of the starting material, dibromosuccinic acid. The S, S enantiomer is present as a dianion and the R, R enantiomer as the neutral acid; both of these components lie on twofold rotation axes. The structure features a complex two-dimensional network of hydrogen bonds.

Place, publisher, year, edition, pages
2006. Vol. 62, O1281-O1283 p.
URN: urn:nbn:se:kth:diva-15572DOI: 10.1107/s1600536806007628ISI: 000236470100150ScopusID: 2-s2.0-33744942348OAI: diva2:333613
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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