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Synthesis of chiral salen Mn(III) complexes covalently linked to Re(I)-based photosensitizers
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2006 (English)In: Journal of coordination chemistry (Print), ISSN 0095-8972, Vol. 59, no 5, 475-484 p.Article in journal (Refereed) Published
Abstract [en]

Two Mn(III)Re(I) binuclear complexes were prepared as catalyst-photosensitizer models, in which the chiral pyrrolidine salen Mn(III) unit was covalently bonded to an Re(I) bipyridyl carbonyl moiety via a carboxamide linkage. The spectral and electrochemical properties of the Mn(III)Re(I) complexes were studied.

Place, publisher, year, edition, pages
2006. Vol. 59, no 5, 475-484 p.
Keyword [en]
manganese complex, rhenium complex, heterobinuclear complex, chiral salen ligand, pyrrolidine, light-driven catalyst, tricarbonylrhenium(i) halide-complexes, intramolecular electron-transfer, stereochemical rearrangements, photophysical properties, solution stereodynamics, carbonyl-complexes, tris-bipyridine, ligand, rhenium(i), epoxidation
URN: urn:nbn:se:kth:diva-15649DOI: 10.1080/00958970500356452ISI: 000237166200003ScopusID: 2-s2.0-33646558568OAI: diva2:333691
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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