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Fe3O4 and gamma-Fe2O3 nanoparticles for the adsorption of Co2+ from aqueous solution
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.
KTH, School of Industrial Engineering and Management (ITM), Materials Science and Engineering.
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry.
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2006 (English)In: Journal of Colloid and Interface Science, ISSN 0021-9797, E-ISSN 1095-7103, Vol. 298, no 2, 501-507 p.Article in journal (Refereed) Published
Abstract [en]

The adsorption of Co2+ ions from nitrate solutions using iron oxide nanoparticles of magnetite (Fe3O4) and maghemite (gamma-Fe2O3) has been studied. The adsorption of Co2+ ions on the surface of the particles was investigated under different conditions of oxide content, contact time, Solution pH. and initial Co2+ ion concentration. It has been found that the equilibrium can be attained in less than 5 ruin. The maximum loading capacity of Fe3O4 and gamma-Fe2O3 nanoparticles is 5.8 x 10(-5) and 3.7 x 10(-5) mol m(-2), respectively, which are much higher than the previously Studied. iron oxides and conventional ion exchange resins. Co2+ ions were also recovered by dilute nitric acid from the loaded gamma-Fe2O3 and Fe3O4 with an efficiency of 86 and 30%. respectively. That has been explained by the different mechanisms by including both the surface and Structural loadings of Co2+ ions. The Surface adsorption of Co2+ on Fe3O4 and gamma-Fe2O3 nanoparticles has been found to have the same mechanism of ion exchange reaction between Co2+ in the solution and proton bonded on the particle Surface. The conditional equilibrium constants of surface 2-adsorption of Co2+ on Fe3O4 and gamma-Fe-O-2(3) nanoparticles have been determined to be log K = -3.3 +/- 0.3 and -3.1 +/- 0.2, respectively. The Structural loading of Co2+ ions into Fe3O4 lattice has been found to be the ion exchange reaction between CO2+ and Fe2+ while that into gamma-Fe2O3 lattice to fill its vacancy. The effect of temperature on the adsorption of Co2+ was also investigated, and the value of enthalpy change was determined to be 19 kJ mol(-1)

Place, publisher, year, edition, pages
2006. Vol. 298, no 2, 501-507 p.
Keyword [en]
adsorption, magnetite, maghemite, cobalt(II), nanoparticles, magnetite particles, reaction-kinetics, iron-oxide, ions, hematite, goethite, cadmium, desorption, cobalt(ii), sorption
National Category
Materials Chemistry
Identifiers
URN: urn:nbn:se:kth:diva-15713DOI: 10.1016/j.jcis.2005.12.057ISI: 000237909100001Scopus ID: 2-s2.0-33747758390OAI: oai:DiVA.org:kth-15713DiVA: diva2:333755
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved
In thesis
1. Selective Separation of Metal Ions by Solvent Extraction, Liquid Membranes and Magnetic Nanoparticles
Open this publication in new window or tab >>Selective Separation of Metal Ions by Solvent Extraction, Liquid Membranes and Magnetic Nanoparticles
2006 (English)Doctoral thesis, comprehensive summary (Other scientific)
Place, publisher, year, edition, pages
Stockholm: KTH, 2006. xvi, 50 p.
Keyword
solvent extraction, facilitated transport, Pt(IV), Pd(II), Ph(III), permeation medelling, thermodynamic modelling
National Category
Materials Chemistry
Identifiers
urn:nbn:se:kth:diva-3871 (URN)91-7178-218-8 (ISBN)
Public defence
2006-03-17, Salongen, KTHB, Osquars backe 31, Stockholm, 10:00
Opponent
Supervisors
Note
QC 20100924Available from: 2006-03-08 Created: 2006-03-08 Last updated: 2010-09-24Bibliographically approved

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