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Aryl-diamide bridged binuclear ruthenium(II) tris(bipyridine) complexes: Synthesis, photophysical, electrochemical and electrochemiluminescence properties
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2006 (English)In: Journal of Organometallic Chemistry, ISSN 0022-328X, E-ISSN 1872-8561, Vol. 691, no 20, 4189-4195 p.Article in journal (Refereed) Published
Abstract [en]

Several new symmetrical aromatic hydrocarbon bridged bipyridine ligands and their binuclear Ru (II) complexes have been designed, synthesized and characterized on the basis of H-1 NMR, MS and HRMS. Their absorption and emission properties, electrochemical behaviors and electrochemical luminescence were investigated. All ruthenium complexes show characteristic MLCT absorption and similar redox potential. Among the three complexes reported, 4c has the best electrochemical luminescence property.

Place, publisher, year, edition, pages
2006. Vol. 691, no 20, 4189-4195 p.
Keyword [en]
binuclear ruthenium complexes, electrochemiluminescence, polypyridine ligands, synthesis, electrogenerated chemiluminescence, high-brightness, heck reaction, ligands, devices, emitter, ecl, luminescence, bipyridine, emission
URN: urn:nbn:se:kth:diva-16051DOI: 10.1016/j.jorganchem.2006.06.034ISI: 000241213100005ScopusID: 2-s2.0-33747876104OAI: diva2:334093
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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