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Bidentate phosphine ligand based Fe2S2-containing macromolecules: Synthesis, characterization, and catalytic electrochemical hydrogen production
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2006 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 45, no 23, 9169-9171 p.Article in journal (Refereed) Published
Abstract [en]

The reaction of [Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N(mu-SCH2)(2)Fe-2(CO)(6)] (1) with 1,2-bis(diphenylphosphino) ethane in the presence of Me3NO, 2H(2)O affords two structurally different metallomacromolecules: a dimer of the type [{Fe-2(CO)(5)(mu-SCH2)(2)NCH2CH2N(mu-SCH2) Fe-2(2)(CO)(5)}(Ph2PCH2)(2)] (2) and a tetramer species containing eight iron centers with an overall formula of [{Fe-2(CO)(6)(mu-SCH2)(2)NCH2CH2N( mu-SCH2)(2)Fe-2(CO)(5)}(2)(Ph2PCH2)(2)] (3). Their structures have been determined by X-ray crystallography, showing one macrocyclic complex (2) and one linear complex (3). Electrochemical hydrogen evolution catalyzed by these two complexes with ca. 80-90 single-run turnovers is observed, indicating good potential as catalysts for future applications.

Place, publisher, year, edition, pages
2006. Vol. 45, no 23, 9169-9171 p.
Keyword [en]
fe-only hydrogenases, active-site models, functional models, evolution
Identifiers
URN: urn:nbn:se:kth:diva-16110DOI: 10.1021/ic061258eISI: 000241778900008Scopus ID: 2-s2.0-33751280975OAI: oai:DiVA.org:kth-16110DiVA: diva2:334152
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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