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Catalysed low temperature H-2 release from nitrogen heterocycles
KTH, School of Biotechnology (BIO), Theoretical Chemistry.ORCID iD: 0000-0003-0007-0394
2006 (English)In: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 30, no 11, 1675-1678 p.Article in journal (Refereed) Published
Abstract [en]

In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H-2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 degrees C.

Place, publisher, year, edition, pages
2006. Vol. 30, no 11, 1675-1678 p.
Keyword [en]
molecular-orbital methods, noble-metal catalysts, carbon nanotubes, dehydrogenation, hydrogen, storage, complexes, evolution, energies, alcohols
URN: urn:nbn:se:kth:diva-16117DOI: 10.1039/b608914cISI: 000241886100021ScopusID: 2-s2.0-33750817128OAI: diva2:334159
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Luo, Yi
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