Catalysed low temperature H-2 release from nitrogen heterocycles
2006 (English)In: New Journal of Chemistry, ISSN 1144-0546, E-ISSN 1369-9261, Vol. 30, no 11, 1675-1678 p.Article in journal (Refereed) Published
In an experimental and computational study, nitrogen- and oxygen-containing heterocycles were compared with carbocycles as liquid substrates for hydrogen release with heterogeneous catalysts. Heteroatom substitution, particularly by nitrogen, favours low temperature H-2 release; indoline was fully dehydrogenated in less than 30 min with Pd/C at 110 degrees C.
Place, publisher, year, edition, pages
2006. Vol. 30, no 11, 1675-1678 p.
molecular-orbital methods, noble-metal catalysts, carbon nanotubes, dehydrogenation, hydrogen, storage, complexes, evolution, energies, alcohols
IdentifiersURN: urn:nbn:se:kth:diva-16117DOI: 10.1039/b608914cISI: 000241886100021ScopusID: 2-s2.0-33750817128OAI: oai:DiVA.org:kth-16117DiVA: diva2:334159
QC 201005252010-08-052010-08-05Bibliographically approved