Change search
ReferencesLink to record
Permanent link

Direct link
A new, dinuclear high spin manganese(III) complex with bridging phenoxy and methoxy groups. Structure and magnetic properties
Show others and affiliations
2006 (English)In: Inorganic Chemistry Communications, ISSN 1387-7003, E-ISSN 1879-0259, Vol. 9, no 12, 1195-1198 p.Article in journal (Refereed) Published
Abstract [en]

A new mu-phenoxy-mu-metoxy di-manganese(III) complex with the trisphenolic ligand, 2,6-bis[((2-hydroxybenzyl)(2-pyridylmethyl)amino)methyl]-4-methylphenol, was isolated as a perchlorate salt. The X-ray structure shows that the two manganese(III) ions are in a distorted octrahedral enviroment with approximately perpendicular Jahn-Teller axes. Investigation of the molar magnetic susceptibility reveals a ferromagnetic coupling between the two high-spin manganese(III) ions. Fitting of the data led to g = 2 and J = 12.5 cm(-1).

Place, publisher, year, edition, pages
2006. Vol. 9, no 12, 1195-1198 p.
Keyword [en]
manganese complex, X-ray structure, magnetic properties, photosynthetic water oxidation, photosystem-ii, phenolate ligands, tris-bipyridine, model, catalysts, enzymes, epr
URN: urn:nbn:se:kth:diva-16186DOI: 10.1016/j.inoche.2006.07.025ISI: 000242615800011ScopusID: 2-s2.0-33751114952OAI: diva2:334228
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Search in DiVA

By author/editor
Sun, Licheng
By organisation
Organic Chemistry
In the same journal
Inorganic Chemistry Communications

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 39 hits
ReferencesLink to record
Permanent link

Direct link