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Syntheses and crystal structures of new palladium(II) and platinum(IV) trialkylsulfonium compounds
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2007 (English)In: Zeitschrift für Anorganische und Allgemeines Chemie, ISSN 0044-2313, E-ISSN 1521-3749, Vol. 633, no 4, 643-646 p.Article in journal (Refereed) Published
Abstract [en]

The reactions of platinum(II) iodide with triethyl- or trimethylsulfonium iodide in acetonitrile solution lead to the formation of crystalline products (Et3S)(2)[PtI6] (1) and [Me3S]=[PtI6]center dot CH3CN (2), respectively. The formation of Pt(IV) complexes may be explained either by disproportionation of PtI2 or oxidation by oxygen. Palladium(II) iodide reacts with triethylsulfonium iodide to give the palladium(II) complex (Et3S)(2)[PdI4] (3). The crystal structures of 1-3 were determined by single-crystal X-ray diffraction. In the crystal structures, the compounds 2 and 3 exhibit an extensive hydrogen-bonding network.

Place, publisher, year, edition, pages
2007. Vol. 633, no 4, 643-646 p.
Keyword [en]
platinum, palladium, sulfonium, ionic liquid, crystal structure, nanocrystalline solar-cells, ionic liquids, electrolytes, molten, polyiodides, complexes, iodides, salts
Identifiers
URN: urn:nbn:se:kth:diva-16484DOI: 10.1002/zaac.200600391ISI: 000245182100024Scopus ID: 2-s2.0-33947575961OAI: oai:DiVA.org:kth-16484DiVA: diva2:334526
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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