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Elastic peak of K shell excited HCl molecule: Comparison HCl-DCl - Experiment and theory
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2007 (English)In: Journal of Electron Spectroscopy and Related Phenomena, ISSN 0368-2048, Vol. 155, no 1-3, 91-94 p.Article in journal (Refereed) Published
Abstract [en]

Fermosecond dynamics has been recently observed by resonant X-ray Raman scattering (RXRS) after excitation along the dissociative Cl 1s -> 6 sigma* resonance of gas phase HCl. In this paper, we show a method to take into account and correct for self-absorption of the elastic peak, in order to allow for quantitative comparison with theory. We have performed measurements on the DCl molecule exhibiting ultrafast nuclear motion. A comparison between HCl and DCl is presented.

Place, publisher, year, edition, pages
2007. Vol. 155, no 1-3, 91-94 p.
Keyword [en]
RIXS, RXRS, HCl, DCl, elastic peak, self-absorption, nuclear motion, ray raman-scattering, fast dissociation, decay, excitation
National Category
Theoretical Chemistry
URN: urn:nbn:se:kth:diva-16528DOI: 10.1016/j.elspec.2006.11.007ISI: 000245493900017ScopusID: 2-s2.0-33847650891OAI: diva2:334570
Conference: International Symposium on Scattering, Coincidence and Absorption Studies of Molecules. Fed Univ Rio de Janeiro, Rio de Janeiro, BRAZIL. SEP 04-06, 2006Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2011-09-13Bibliographically approved

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Minkov, IvayloGel'mukhanov, FarisSalek, PawelÅgren, Hans
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Theoretical Chemistry and BiologyTheoretical Chemistry (closed 20110512)
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