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Facile and highly efficient light-induced PR3/CO ligand exchange: A novel approach to the synthesis of (mu-(SCH2NPrCH2S)-Pr-n)Fe-2(CO)(4)(PR3)(2)
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2007 (English)In: Journal of Organometallic Chemistry, ISSN 0022-328X, E-ISSN 1872-8561, Vol. 692, no 7, 1579-1583 p.Article in journal (Refereed) Published
Abstract [en]

A straightforward and efficient transformation of the Fe-S complex [(mu-SCH2NPrCH2S)Fe-2(CO)(6)] to its double phosphine coordinated analogues [(mu-(SCH2NPrCH2S)-Pr-n)Fe-2(CO)(4)(PR3)(2)] (R = Ph, Me) is described. The single crystal structure of the PPh3-disubstituted Complex [(mu-(SCH2NPrCH2S)-Pr-n)Fe-2(CO)(4)(Ph3P)(2)] (3) showed that both of the phosphine ligands take an apical/apical instead of a basal/ basal or an apical/basal configuration.

Place, publisher, year, edition, pages
2007. Vol. 692, no 7, 1579-1583 p.
Keyword [en]
Fe-hydrogenases, phosphine ligands, bioinorganic chemistry, hydrogen production, hydrogenase active-site, fe-only hydrogenase, electrochemical properties, functional models, iron, complexes, sulfides
URN: urn:nbn:se:kth:diva-16630DOI: 10.1016/j.jorganchem.2006.12.009ISI: 000246468400017ScopusID: 2-s2.0-33846809080OAI: diva2:334672
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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