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Investigations of the 2,3 -sigmatropic rearrangements of vinylaziridines and allylic amines
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.
2007 (English)In: Synlett: Accounts and Rapid Communications in Synthetic Organic Chemistry, ISSN 0936-5214, E-ISSN 1437-2096, no 8, 1190-1202 p.Article in journal (Refereed) Published
Abstract [en]

This account summarizes our studies of [2,3]-sigmatropic rearrangements of vinylaziridines and allylic amines. The scope and limitations of the reactions as well as our present mechanistic understanding are also discussed.

Place, publisher, year, edition, pages
2007. no 8, 1190-1202 p.
Keyword [en]
rearrangements, vinylaziridines, ylides, pericyclic reactions, asymmetric reactions, enantioselective total-synthesis, ammonium ylides, aza-<2, 3>-wittig rearrangements, <2, 3>-wittig rearrangement, sigmatropic rearrangement, indolizidine alkaloids, organosulfur compounds, carbon configuration, n-allyl, alcohols
National Category
Chemical Sciences
Identifiers
URN: urn:nbn:se:kth:diva-16689DOI: 10.1055/s-2007-980341ISI: 000247217700002Scopus ID: 2-s2.0-34249827253OAI: oai:DiVA.org:kth-16689DiVA: diva2:334732
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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