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Synthesis and photophysical and electrochemical properties of a binuclear Ru(bpy)(3)-Cu(III) corrole complex
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2007 (English)In: Journal of Porphyrins and Phthalocyanines, ISSN 1088-4246, E-ISSN 1099-1409, Vol. 11, no 06-maj, 463-469 p.Article in journal (Refereed) Published
Abstract [en]

A novel binuclear Ru-Cu complex, composed of a copper(III)-corrole and a ruthenium(II) tris(bipyridine) moicty linked by an amide bond, has been synthesized and characterized by H-1 NMR, UV-vis and mass spectrometry. The steady-state emission and the electrochemical properties were investigated. Compared to the parent [Ru(bpy)(3)](2+), the emission-of the desired complex was substantially quenched when the MLCT of [Ru(bpy)(3)](2+) was selectively photoexcited.

Place, publisher, year, edition, pages
2007. Vol. 11, no 06-maj, 463-469 p.
Keyword [en]
Cu(III) corrole, [Ru(bpy)(3)](2+), OEC, photosystem II, water oxidation, photoinduced electron-transfer, oxygen-evolving center, free-base corroles, photosystem-ii, water-oxidation, crystal-structure, copper corroles, energy-transfer, 1st synthesis, porphyrin
URN: urn:nbn:se:kth:diva-16788ISI: 000247991400020ScopusID: 2-s2.0-34447315298OAI: diva2:334831
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Sun, Licheng
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Organic Chemistry
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