Change search
ReferencesLink to record
Permanent link

Direct link
Ruthenium(II,III,III) mu(3)-oxotrifluoroacetate with dimethyl sulfoxide: Synthesis, structure, and DTF quantum-chemical calculations
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
Show others and affiliations
2007 (English)In: Russian journal of coordination chemistry, ISSN 1070-3284, E-ISSN 1608-3318, Vol. 33, no 9, 669-673 p.Article in journal (Refereed) Published
Abstract [en]

The reaction of [Ru-3(III) (mu(3)-O)(mu-O2CCF3)(6)(H2O)(3)](O2CCF3) in methanol gives two solvates, [Ru3O(O2CCF3)(6)(DMSO)(3)] center dot 1/2H(2)O (I) and [Ru3O(O2CCF3)(6)(DMSO)(3)] center dot H2O (II), of a novel trinuclear mixedvalence Ru(II,III,III) trifluoroacetate complex, where two DMSO molecules are coordinated to the Ru atoms through the O atom, while the third DMSO molecule is coordinated through the S atom. According to the X-ray diffraction data, the complex can crystallize in two crystal systems: triclinic (I) (space group P (1) over bar) and monoclinic (II) (space group P2(1)/m). The unit cell parameters for I are: a = 9.354, b = 11.005, c = 20.846 angstrom, alpha = 99.10, beta = 96.38, gamma = 92.17, Z = 2; R = 7.27%; for I are: a = 9.186, b = 17.044, c = 13.091 angstrom, beta = 101.10, Z = 2; R = 14.18%.

Place, publisher, year, edition, pages
2007. Vol. 33, no 9, 669-673 p.
Keyword [en]
carboxylate, complexes, cluster
URN: urn:nbn:se:kth:diva-16965ISI: 000249630300008OAI: diva2:335008
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

Open Access in DiVA

No full text

Search in DiVA

By author/editor
Gorlov, Mikhail
By organisation
Inorganic Chemistry
In the same journal
Russian journal of coordination chemistry

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Total: 23 hits
ReferencesLink to record
Permanent link

Direct link