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Effect of deprotonation of a benzimidazolyl ligand on the redox potential and the structures of mononuclear ruthenium(II) complexes
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2007 (English)In: European Journal of Inorganic Chemistry, ISSN 1434-1948, E-ISSN 1099-0682, no 26, 4128-4131 p.Article in journal (Refereed) Published
Abstract [en]

A monoruthenium(II) complex of the benzimidazolyl ligand and its deprotonated counterpart were prepared and structurally characterized. The reversible protonation/deprotonation process of the ancillary ligand switches the redox potential of the ruthenium(II) core from 0.69 to 0.26 V vs. Ag/AgNO3. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)

Place, publisher, year, edition, pages
2007. no 26, 4128-4131 p.
Keyword [en]
benzimidazolyl ligand, redox switch, reversible protonation and deprotonation, Ru-II complex, cytochrome-c-oxidase, dinuclear ruthenium, photophysical properties, spectroscopic properties, isomeric complexes, crystal-structure, pyrazole-3,5-bis(benzimidazole), oxidation, state, acid
URN: urn:nbn:se:kth:diva-16979DOI: 10.1002/ejic.200700549ISI: 000249767700004ScopusID: 2-s2.0-34748894432OAI: diva2:335022
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Sun, Licheng
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