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Supramolecular self-assembly of a 2Fe2S complex with a hydrophilic phosphine ligand
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2008 (English)In: CrystEngComm, ISSN 1466-8033, E-ISSN 1466-8033, Vol. 10, no 3, 267-269 p.Article in journal (Refereed) Published
Abstract [en]

A diiron complex [{(mu-SCH2)(2)CH2}{Fe-2(CO)(5)P(CH2OH)(3)}] was prepared as a biomimic of the [2Fe2S] subunit in the active site of [FeFe] hydrogenases, which appears as a supramolecular self-assembly in the solid state with O-H center dot center dot center dot O hydrogen bonds forming two-dimensional arrays with alternately right- and left-handed helical O-H center dot center dot center dot O-H chains.

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2008. Vol. 10, no 3, 267-269 p.
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URN: urn:nbn:se:kth:diva-17349DOI: 10.1039/b713159cISI: 000253642200002Scopus ID: 2-s2.0-39749086510OAI: oai:DiVA.org:kth-17349DiVA: diva2:335393
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QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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Sun, Licheng

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