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cis-(9S,10S)-Methyl 1-propyl-1,2,3,4-tetrahydro-beta-carboline-3-carboxylate
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
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2008 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 64, O361-U1624 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, C16H20N2O2, was synthesized from ( S)tryptophan methyl ester hydrochloride and butyraldehyde. The absolute configuration 9S, 10S was assigned on the basis of the unchanging chirality of the C9 centre. The NH group of the indole ring is involved in intermolecular N-H center dot center dot center dot O hydrogen bonding, while the NH group of the six-membered ring is not. This latter ring has a half-chair conformation.

Place, publisher, year, edition, pages
2008. Vol. 64, O361-U1624 p.
URN: urn:nbn:se:kth:diva-17361DOI: 10.1107/s1600536807066020ISI: 000253779700153ScopusID: 2-s2.0-38949128712OAI: diva2:335405
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Fischer, Andreas
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Inorganic Chemistry
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