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trans-Diaquabis(ethylenediamine-kappa N-2,N '') copper(II) bis 3-(3-pyridyl)-propionate dihydrate
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
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2008 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 64, M509-U35 p.Article in journal (Refereed) Published
Abstract [en]

The asymmetric unit of the title complex, [Cu(C2H8N2)(2)-(H2O)(2)](C8H8NO2)(2)center dot 2H(2)O, contains one anion, one half-cation and one water molecule. The Cu-II atom in the [Cu(en)(2)(H2O)(2)](2+) cation (en is ethylenediamine) lies on an inversion centre. The four N atoms of the en ligands in the equatorial plane around the Cu-II atom form a slightly distorted square-planar arrangement, while the slightly distorted Jahn-Teller octahedral coordination is completed by two water O atoms in axial positions. In the crystal structure, intra- and intermolecular N - H center dot center dot center dot O and O - H center dot center dot center dot O hydrogen bonds form a three-dimensional network.

Place, publisher, year, edition, pages
2008. Vol. 64, M509-U35 p.
Identifiers
URN: urn:nbn:se:kth:diva-17418DOI: 10.1107/s1600536808005400ISI: 000254528300003Scopus ID: 2-s2.0-41849137928OAI: oai:DiVA.org:kth-17418DiVA: diva2:335462
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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