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One-dimensional chloro-bridged Cd(II) chains separated by dimethyl hexadecyl sulfonium cation layers: synthesis and structure
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2008 (English)In: Structural Chemistry, ISSN 1040-0400, E-ISSN 1572-9001, Vol. 19, no 1, 51-55 p.Article in journal (Refereed) Published
Abstract [en]

A low-dimensional material with the composition {(n-C16H33)(CH3)(2)S}(infinity)(+1)[CdCl3](-) has been prepared. As expected, the sulfonium cations form an insulating organic layer; the closest Cd-Cd distance between layers is about 19 angstrom, as compared to 3.9 angstrom within the same layer. The inorganic layer is formed by a 5-coordinated cadmium(II) moiety CdCl5, connected to a one-dimensional chain of slightly distorted, edge-sharing square pyramids. The compound was synthesized from the parent sulfonium chloride and CdCl2 in ethanol, exploiting the Lewis acidity of Cd(II).

Place, publisher, year, edition, pages
2008. Vol. 19, no 1, 51-55 p.
Identifiers
URN: urn:nbn:se:kth:diva-17526DOI: 10.1007/s11224-007-9248-9ISI: 000255750500008Scopus ID: 2-s2.0-43049088129OAI: oai:DiVA.org:kth-17526DiVA: diva2:335570
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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