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Synthesis and structure of a mu-oxo diiron(III) complex with an N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine ligand and its catalytic property for hydrocarbon oxidation
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2008 (English)In: Applied organometallic chemistry, ISSN 0268-2605, E-ISSN 1099-0739, Vol. 22, no 10, p. 573-576Article in journal (Refereed) Published
Abstract [en]

A mu-oxo diiron(III) complex [{Fe(pbba)Cl}(2)(mu-O)]Cl-2 (1, pbba = N-pyridylmethyl-N,N-bis(4-methylbenzimidazol-2-yl)amine) bearing multi-imidazolyl motifs was synthesized and characterized by X-ray crystallography to closely mimic the structural features of methane monooxygenase. As shown by its X-ray crystal structure, complex 1 is a centrosymmetric dimer with an Fe-O-Fe angle of 180 degrees, and pseudo-octahedral around each iron(III) center. The catalytic ability of title compound in the oxidation of alkane and alkene is investigated by employing tert-butylhydroperoxide and m-chloroperbenzoic acid as oxidants under mild conditions. The catalytic oxidation results showed that radical intermediate dominates the oxidation process.

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2008. Vol. 22, no 10, p. 573-576
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URN: urn:nbn:se:kth:diva-17866DOI: 10.1002/aoc.1444ISI: 000259780600004Scopus ID: 2-s2.0-53449093027OAI: oai:DiVA.org:kth-17866DiVA, id: diva2:335911
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QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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Sun, Licheng

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