A proton-hydride diiron complex with a base-containing diphosphine ligand relevant to the FeFe -hydrogenase active site
2008 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 44, 5800-5802 p.Article in journal (Refereed) Published
A diiron dithiolate complex holding a mu-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the H-mu(-)center dot center dot center dot H-N(+) distance is 3.934 angstrom.
Place, publisher, year, edition, pages
2008. no 44, 5800-5802 p.
IdentifiersURN: urn:nbn:se:kth:diva-17970DOI: 10.1039/b811352aISI: 000260889800038ScopusID: 2-s2.0-56349134963OAI: oai:DiVA.org:kth-17970DiVA: diva2:336015
QC 201005252010-08-052010-08-05Bibliographically approved