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A proton-hydride diiron complex with a base-containing diphosphine ligand relevant to the FeFe -hydrogenase active site
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2008 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 44, 5800-5802 p.Article in journal (Refereed) Published
Abstract [en]

A diiron dithiolate complex holding a mu-hydride on the iron atoms and a proton on the basic site of a chelating diphosphine ligand was prepared and crystallographically characterized as a structural model of the [FeFe]-hydrogenase active site, and its molecular structure shows the H-mu(-)center dot center dot center dot H-N(+) distance is 3.934 angstrom.

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2008. no 44, 5800-5802 p.
URN: urn:nbn:se:kth:diva-17970DOI: 10.1039/b811352aISI: 000260889800038ScopusID: 2-s2.0-56349134963OAI: diva2:336015
QC 20100525Available from: 2010-08-05 Created: 2010-08-05Bibliographically approved

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Sun, Licheng
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Organic Chemistry
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