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Dimeric palladium and platinum complexes isolated in Lewis-acidic media
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2009 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 362, no 2, 605-609 p.Article in journal (Refereed) Published
Abstract [en]

The synthesis and X-ray characterization of binuclear dipalladium(I) and diplatinum(I) p-xylene complexes [Pd-2(eta(6)-C8H10)(2)(mu-Cl/Br)(2)(GaCl3)(2)] (1) and [Pt-2(eta(6)-C8H10)(2)(Ga2Br7)(2)] (5) are reported. It was established that the toluene ligands in the palladium complex [Pd-2(eta(6)-C7H8)(2)(GaCl4)(2)] (3) can be substituted by naphthalene without disruption of the metal-metal bond. The reaction of 3 with Pd(PPh3)(4) leads to the formation of a dipalladium(II) mu-diphenylphosphido compound [Pd2(mu- PPh2)(PPh3)(4)] (GaCl4)(2) center dot 4(C7H8) (4), most likely also involving a bridging mu-H ligand.

Place, publisher, year, edition, pages
2009. Vol. 362, no 2, 605-609 p.
Identifiers
URN: urn:nbn:se:kth:diva-18074DOI: 10.1016/j.ica.2008.04.006ISI: 000261995300047Scopus ID: 2-s2.0-57749114854OAI: oai:DiVA.org:kth-18074DiVA: diva2:336120
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2010-12-22Bibliographically approved

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Gorlov, MikhailFischer, AndreasKloo, Lars A.
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