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Electrogenerated chemiluminescence, of benzo 15-crown-5 derivatives
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2009 (English)In: Journal of Physical Organic Chemistry, ISSN 0894-3230, E-ISSN 1099-1395, Vol. 22, no 1, 1-8 p.Article in journal (Refereed) Published
Abstract [en]

Novel electrogenerated chemiluminescence (ECL) reagents C1, C2, and C3 with high fluorescence quantum yields bearing 15-crown-5 moiety have been synthesized and characterized. The photophysical, electrochemical, and ECL characters of these compounds have been studied in a 1:1 (v/v) PhH/MeCN mixed solvent. The ECL intensity is enhanced distinctly with the increase in the fluorescence quantum yield. Their ECL behaviors have been studied using annihilation and co-reactant methods (tri-n-propylamine (TPrA) was used as a co-reactant), respectively. The stable ECL emissions of compounds C1-C3 can be ascribed to the typical and simple monomer ECL emission via S-route.

Place, publisher, year, edition, pages
2009. Vol. 22, no 1, 1-8 p.
URN: urn:nbn:se:kth:diva-18086DOI: 10.1002/poc.1414ISI: 000262268200001ScopusID: 2-s2.0-59449102522OAI: diva2:336132
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2011-02-09Bibliographically approved

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