Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Nucleophilic Attack of Hydroxide on a Mn-V Oxo Complex: A Model of the O-O Bond Formation in the Oxygen Evolving Complex of Photosystem II
KTH, School of Chemical Science and Engineering (CHE), Chemical Engineering and Technology, Applied Electrochemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
Show others and affiliations
2009 (English)In: Journal of the American Chemical Society, ISSN 0002-7863, E-ISSN 1520-5126, Vol. 131, no 25, 8726-+ p.Article in journal (Refereed) Published
Abstract [en]

A manganese(III) corrole complex, 1, has been synthesized and used to study a potential mechanism for oxidation of water to molecular oxygen. Oxidation by t-BuOOH gave the Mn-V=O complex 2. Addition of hydroxide Led to release of oxygen via the Mn-IV complex 4 and regeneration of complex 1. It could be shown that the oxygen from O-18-labeted water was incorporated in both the formed molecular oxygen and the peroxy intermediate 4.

Place, publisher, year, edition, pages
2009. Vol. 131, no 25, 8726-+ p.
Keyword [en]
photosynthetic water oxidation, oxomanganese(v) porphyrin, manganese, corroles, compound-i, evolution, spectroscopy, peroxidase, catalysis
Identifiers
URN: urn:nbn:se:kth:diva-18568DOI: 10.1021/ja901139rISI: 000267631000004Scopus ID: 2-s2.0-67649610433OAI: oai:DiVA.org:kth-18568DiVA: diva2:336615
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full textScopus

Authority records BETA

Sun, Licheng

Search in DiVA

By author/editor
Åkermark, TorbjörnSun, Licheng
By organisation
Applied ElectrochemistryOrganic Chemistry
In the same journal
Journal of the American Chemical Society

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 57 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf