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Light-driven hydrogen production catalysed by transition metal complexes in homogeneous systems
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Organic Chemistry.ORCID iD: 0000-0002-4521-2870
2009 (English)In: Dalton Transactions, ISSN 1477-9226, E-ISSN 1477-9234, no 33, 6458-6467 p.Article in journal (Refereed) Published
Abstract [en]

The development of heterogeneous catalytic systems for hydrogen production from water under light irradiation has been investigated during last three decades. Homogeneous photocatalysts, however, are very attractive in sense that their chemical and photochemical properties can be understood and tuned on molecular level. Moreover, in homogeneous systems catalysts may be covalently bound to photosensitizers, which leads to more efficient electron transfer. Molecular devices for water splitting based on such a systems are of great interest. In this review, we summarize recent progresses in the synthesis, properties and application of metal-based molecular catalysts for photoinduced hydrogen evolution in homogeneous systems.

Place, publisher, year, edition, pages
2009. no 33, 6458-6467 p.
URN: urn:nbn:se:kth:diva-18683DOI: 10.1039/b903809dISI: 000268885800002ScopusID: 2-s2.0-68749103448OAI: diva2:336730
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2011-01-25Bibliographically approved

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