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2-Bromomaleic acid
KTH, School of Chemical Science and Engineering (CHE), Chemistry, Inorganic Chemistry.
2009 (English)In: Acta Crystallographica Section E: Structure Reports Online, ISSN 1600-5368, E-ISSN 1600-5368, Vol. 65, O2240-U2786 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, C4H3BrO4, was obtained from a solution of meso-2,3-dibromosuccinic acid and vanadium(IV) oxide. The crystals are isostructural with chloromaleic acid and the molecule has two geometrically different carboxyl groups, one of which has delocalized C-O bonds and is essentially coplanar with the olefinic bond plane [give dihedral angle 15.08 (16)degrees], whereas the other has a localized C=O bond and forms a dihedral angle of 99.6 (3)degrees with the C C bond plane. Two symmetry-independent O-H center dot center dot center dot O hydrogen bonds link the molecules into layers parallel to the bc plane.

Place, publisher, year, edition, pages
2009. Vol. 65, O2240-U2786 p.
Identifiers
URN: urn:nbn:se:kth:diva-18729DOI: 10.1107/s1600536809029602ISI: 000269523400253Scopus ID: 2-s2.0-70249119620OAI: oai:DiVA.org:kth-18729DiVA: diva2:336776
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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