Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
InSb-TiOPc interfaces: Band alignment, ordering and structure dependent HOMO splitting
KTH, School of Information and Communication Technology (ICT), Microelectronics and Applied Physics, MAP.
KTH, School of Information and Communication Technology (ICT), Microelectronics and Applied Physics, MAP.
KTH, School of Information and Communication Technology (ICT), Microelectronics and Applied Physics, MAP.
KTH, School of Information and Communication Technology (ICT), Microelectronics and Applied Physics, MAP.ORCID iD: 0000-0002-9663-7705
Show others and affiliations
2009 (English)In: Surface Science, ISSN 0039-6028, E-ISSN 1879-2758, Vol. 603, no 20, 3160-3169 p.Article in journal (Refereed) Published
Abstract [en]

Thin films of titanyl phthalocyanine (TiOPc) have been adsorbed on InSb(1 1 1) (3 x 3) and InSb(1 0 0) c(8 x 2) surfaces and studied with respect to their electronic structure using photoemission (PES), density functional theory (DFT) and scanning tunneling microscopy (STM). The interface chemical interaction is weak in both cases; no adsorbate induced surface band bending is observed and the energy level alignment across the interface is determined by the original position of the substrate Fermi level and the charge neutrality level of the molecule. Room temperature adsorption results in disordered films on both surfaces. The behaviors after annealing are different; on InSb(1 0 0) well-ordered molecular chains form along and on top of the In-rows, whereas on (1 1 1) no long range order is observed. The disorder leads to intermolecular interactions between the titanyl group and neighboring benzene rings leading to a split of TiOPc HOMO (highest occupied molecular orbital) by as much as 0.8 eV.

Place, publisher, year, edition, pages
2009. Vol. 603, no 20, 3160-3169 p.
Keyword [en]
InSb, Phthalocyanine, Organic-inorganic semiconductor interface, Scanning tunneling microscopy, Photoelectron spectroscopy, metal-free phthalocyanine, titanyl-phthalocyanine, electronic-structure, copper-phthalocyanine, thin-film, molecular-orientation, ir sensitization, ultrathin films, single-crystal, growth mode
National Category
Electrical Engineering, Electronic Engineering, Information Engineering
Identifiers
URN: urn:nbn:se:kth:diva-18899DOI: 10.1016/j.susc.2009.09.001ISI: 000271179600019OAI: oai:DiVA.org:kth-18899DiVA: diva2:336946
Note

QC 20100525

Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2016-12-14Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Authority records BETA

Yu, Shun

Search in DiVA

By author/editor
Brena, BarbaraPalmgren, PålNilson, KatharinaYu, ShunHennies, F.Agnarsson, BjörnÖnsten, AnneliMånsson, MartinGöthelid, Mats
By organisation
Microelectronics and Applied Physics, MAP
In the same journal
Surface Science
Electrical Engineering, Electronic Engineering, Information Engineering

Search outside of DiVA

GoogleGoogle Scholar

doi
urn-nbn

Altmetric score

doi
urn-nbn
Total: 82 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf