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Host-guest interaction in propeller-shaped molecules. Part one: Single crystal X-ray analysis of benzylidene-1,1 '-bis-2-naphthol solvent cocrystals
2009 (English)In: Zeitschrift fur Kristallographie, ISSN 0044-2968, Vol. 224, no 10, 499-505 p.Article in journal (Refereed) Published
Abstract [en]

The structures of cocrystals of benzylidene-1,1'-bis-2-naphthol with methanol and ethanol have been studied by single crystal X-ray diffraction and H-1-NMR spectroscopy. The cocrystal structures are stabilized by intra-and inter-molecular hydrogen bonds with the stoichiometry of a 1 : 1 host: guest. The competition experiment in the solid-liquid biphasic system between pair of guests revealed that methanol is preferentially enclathrated over ethanol in all mole fractions.

Place, publisher, year, edition, pages
2009. Vol. 224, no 10, 499-505 p.
URN: urn:nbn:se:kth:diva-18912DOI: 10.1524/zkri.2009.1149ISI: 000271327800005ScopusID: 2-s2.0-70449099440OAI: diva2:336959
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2011-02-04Bibliographically approved

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Fischer, Andreas
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