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Host-guest interaction in propeller-shaped molecules. Part one: Single crystal X-ray analysis of benzylidene-1,1 '-bis-2-naphthol solvent cocrystals
2009 (English)In: Zeitschrift fur Kristallographie, ISSN 0044-2968, Vol. 224, no 10, p. 499-505Article in journal (Refereed) Published
Abstract [en]

The structures of cocrystals of benzylidene-1,1'-bis-2-naphthol with methanol and ethanol have been studied by single crystal X-ray diffraction and H-1-NMR spectroscopy. The cocrystal structures are stabilized by intra-and inter-molecular hydrogen bonds with the stoichiometry of a 1 : 1 host: guest. The competition experiment in the solid-liquid biphasic system between pair of guests revealed that methanol is preferentially enclathrated over ethanol in all mole fractions.

Place, publisher, year, edition, pages
2009. Vol. 224, no 10, p. 499-505
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URN: urn:nbn:se:kth:diva-18912DOI: 10.1524/zkri.2009.1149ISI: 000271327800005Scopus ID: 2-s2.0-70449099440OAI: oai:DiVA.org:kth-18912DiVA, id: diva2:336959
Note
QC 20100525Available from: 2010-08-05 Created: 2010-08-05 Last updated: 2017-12-12Bibliographically approved

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