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Doppler splitting of in-flight auger decay of dissociating oxygen molecules: The localization of delocalized core holes
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2000 (English)In: Physical Review Letters, ISSN 0031-9007, Vol. 84, no 13, 2826-2829 p.Article in journal (Refereed) Published
Abstract [en]

By exploiting the core-excitation-induced dissociation of O-2, we find that the Auger emission exhibits a Doppler-like energy shift. We show this to be a manifestation of localization of the core hole and propose that the problem of core-hole localization versus delocalization in core-hole spectroscopies may be resolved by considering the nature of the measurement.

Place, publisher, year, edition, pages
2000. Vol. 84, no 13, 2826-2829 p.
Keyword [en]
ray raman-scattering, k-edge spectra, auger-spectra, high-resolution, excited states, symmetry, emission, hcl, o2, ionization
URN: urn:nbn:se:kth:diva-19647ISI: 000086062000015OAI: diva2:338339
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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Gel'mukhanov, FarisÅgren, Hans
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