Residual stresses in glass-fiber composites were studied on the micro and meso scales by computational and experimental methods. Transmitted polarized light images of thin sections were compared with 3D finite-element solutions of a sample containing 1410 fibers. Calculated point-wise stresses were derived from a linear thermoelastic model with negligibly small numerical errors. Regions with calculated maximum compressive stresses showed good agreement with experimentally observed optical bands. A material with poor interfacial adhesion showed weaker optical effects indicating fiber/matrix debonding. On the basis of these results it stems likely that irreversible matrix deformation and debonding can take place in the curing phase.