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A regio- and stereodivergent synthesis of vic-amino alcohols
KTH, Superseded Departments, Chemistry.
2000 (English)In: Organic Letters, ISSN 1523-7060, E-ISSN 1523-7052, Vol. 2, no 25, 4087-4089 p.Article in journal (Refereed) Published
Abstract [en]

[GRAPHICS] A regio- and stereodivergent synthesis of vic-amino alcohols starting from vinylepoxides is described. The developed strategy focuses on the propensity of vinylepoxides and vinylaziridines to be ring-opened at the allylic position by suitable nucleophiles and makes use of reactions that perform such tasks selectively with either retention or inversion of configuration.

Place, publisher, year, edition, pages
2000. Vol. 2, no 25, 4087-4089 p.
Keyword [en]
asymmetric-synthesis, 1,2-amino alcohols, beta-amino, enantioselective synthesis, opening reaction, building-blocks, aziridines, efficient, rearrangement, epoxides
Identifiers
URN: urn:nbn:se:kth:diva-20215DOI: 10.1021/ol006736iISI: 000165829200035OAI: oai:DiVA.org:kth-20215DiVA: diva2:338908
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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