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Palladium(II)-catalyzed oxidation of alcohols with air as reoxidant
KTH, Superseded Departments, Chemistry.ORCID iD: 0000-0002-1743-7650
2001 (English)In: Advanced Synthesis and Catalysis, ISSN 1615-4150, E-ISSN 1615-4169, Vol. 343, no 3, 260-263 p.Article in journal (Refereed) Published
Abstract [en]

Oxidation of primary and secondary aliphatic and secondary benzylic alcohols into their corresponding aldehydes and ketones was achieved in good yields with palladium catalysts using air as the reoxidant of palladium. The use of palladacycle 1 resulted in higher yields and a faster reaction than the use of Pd(OAc)(2) as the palladium source.

Place, publisher, year, edition, pages
2001. Vol. 343, no 3, 260-263 p.
Keyword [en]
air, catalysts, homogeneous catalysis, metallacycles, oxidation, palladium, molecular-oxygen, catalyzed oxidation, benzylic alcohols, hydrogen-peroxide, aldehydes, ketones, efficient
URN: urn:nbn:se:kth:diva-20547ISI: 000168248800005OAI: diva2:339243
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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