Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Electrochemical synthesis, X-ray single crystal, IR spectroscopic, and quantum chemical investigation of molybdenum and tungsten hexamethoxides
KTH, Superseded Departments, Chemistry.
2001 (English)In: Inorganic Chemistry, ISSN 0020-1669, E-ISSN 1520-510X, Vol. 40, no 15, p. 3815-3818Article in journal (Refereed) Published
Abstract [en]

The anodic oxidation of molybdenum metal in MeOH at both low anodic and cathodic current density (0.025 A/cm(2)) and electrolyte temperatures kept below 20 degreesC provides sn efficient approach to Mo(OMe)(6) (I). W(OMe)(6) (II) can be obtained from the electrolytes, prepared via anodic dissolution of tungsten, by fractional crystallization. The symmetrically independent units in the structures of I and II, being isomorphous, follow the C-1 (slightly distorted D-2d) symmetry. Theoretical calculations performed for a free molecule of I indicate that this low symmetry may be the result of the packing of the molecules in the crystal, structure and also an inherent property imposed by the bonding in this compound. Crystal data for I: Mo(OMe)(6) at 22 degrees C, a = 7.0976(13), b = 6.6103(12), and c = 12.286(2) Angstrom, beta = 90.068(3)degrees, V= 576.41(18) Angstrom (3), monoclinic P2/n, Z = 2. Crystal data for II: W(OMe)(6) at 22 degreesC, a = 7.1164(19), b = 6.6414(18), and c = 12.304(3) Angstrom, beta = 90.047(5)degrees, V = 581.5(3) Angstrom (3), monoclinic P2/n, Z = 2.

Place, publisher, year, edition, pages
2001. Vol. 40, no 15, p. 3815-3818
Identifiers
URN: urn:nbn:se:kth:diva-20791ISI: 000169861800022OAI: oai:DiVA.org:kth-20791DiVA, id: diva2:339488
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

Open Access in DiVA

No full text in DiVA

Search in DiVA

By author/editor
Kloo, Lars A.
By organisation
Chemistry
In the same journal
Inorganic Chemistry

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 37 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf