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The trigonal-bipyramidal triiodothallium(III) complex TlI3{(CH3)(2)SO}(2)
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2002 (English)In: Acta Crystallographica Section C: Crystal Structure Communications, ISSN 0108-2701, E-ISSN 1600-5759, Vol. 58, m177-m178 p.Article in journal (Refereed) Published
Abstract [en]

The title compound, bis(dimethyl sulfoxide)triiodothallium(III), [TlI3 (C2H6OS)(2)], was crystallized from equimolar amounts of (TlI)-I-I and I-2 in a dimethyl sulfoxide (DMSO) solution. After the initial redox reaction, the thallium(III)- iodo complex forms and precipitates as a DMSO solvate. In the crystal structure, Tl is surrounded by three iodide ligands in the equatorial plane and two O-coordinated DMSO molecules in the axial positions, forming a slightly distorted trigonal bipyramid. The complex lies on a twofold rotation axis, making the DMSO molecules and two of the I atoms crystallographically equivalent.

Place, publisher, year, edition, pages
2002. Vol. 58, m177-m178 p.
Keyword [en]
molecular-structure, crystal
URN: urn:nbn:se:kth:diva-21372DOI: 10.1107/s0108270101020649ISI: 000174328700022OAI: diva2:340070
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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