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Spectroscopic characterisation of indium(III) chloride and mixed ligand complexes
KTH, Superseded Departments, Chemistry.
2002 (English)In: Spectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, E-ISSN 1873-3557, Vol. 58, no 5, 953-957 p.Article in journal (Refereed) Published
Abstract [en]

Acidic solutions of InCl3 plus InBr3 contain mixed halide complexes and solvent extraction yields the four-coordinate anions InClnBr4-n- whose v(In-Cl) and v(In-Br) modes are reported. Two solid products of InCl3 with 15-crown-5 have been identified; crystallisation from aqueous HCl gave a molecular adduct containing InCl3(H2O)(2), whereas the ionic complex [InCl2(15-crown-5)][InCl4] was produced under anhydrous conditions. The vibrational spectra are assigned.

Place, publisher, year, edition, pages
2002. Vol. 58, no 5, 953-957 p.
Keyword [en]
indium chloride complexes, mixed halide complexes of indium, 15-crown-5 complexes, Raman and Far IR spectroscopy, crown-ethers
Identifiers
URN: urn:nbn:se:kth:diva-21380ISI: 000174343700006OAI: oai:DiVA.org:kth-21380DiVA: diva2:340078
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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