Spectroscopic characterisation of indium(III) chloride and mixed ligand complexes
2002 (English)In: Spectrochimica Acta Part A - Molecular and Biomolecular Spectroscopy, ISSN 1386-1425, Vol. 58, no 5, 953-957 p.Article in journal (Refereed) Published
Acidic solutions of InCl3 plus InBr3 contain mixed halide complexes and solvent extraction yields the four-coordinate anions InClnBr4-n- whose v(In-Cl) and v(In-Br) modes are reported. Two solid products of InCl3 with 15-crown-5 have been identified; crystallisation from aqueous HCl gave a molecular adduct containing InCl3(H2O)(2), whereas the ionic complex [InCl2(15-crown-5)][InCl4] was produced under anhydrous conditions. The vibrational spectra are assigned.
Place, publisher, year, edition, pages
2002. Vol. 58, no 5, 953-957 p.
indium chloride complexes, mixed halide complexes of indium, 15-crown-5 complexes, Raman and Far IR spectroscopy, crown-ethers
IdentifiersURN: urn:nbn:se:kth:diva-21380ISI: 000174343700006OAI: oai:DiVA.org:kth-21380DiVA: diva2:340078
QC 201005252010-08-102010-08-10Bibliographically approved