Change search
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf
Novel bis(diethylenetriamine)thallium(III) complex. Synthesis and characterization in pyridine solution and in solid
KTH, Superseded Departments, Chemistry.
2002 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 331, 224-231 p.Article in journal (Refereed) Published
Abstract [en]

A new complex of thallium(ill) with the nitrogen donor ligand diethylenetriamine (dien) has been prepared and characterized by multinuclear NMR (H-1, C-13. Tl-205), infrared and Raman spectroscopy. and X-ray diffraction. In solution, the symmetric s-facial isomer of [Tl(dien)(2)](3+) is formed. This is a fluxional molecule even at low temperature (235 K): therefore, the different rotamers cannot be observed separately. A complete characterization of the complex is given from its non-trivial NMR spectra. The crystal structure of [Tl(dien)(2)](ClO4)(3).H2O shows u-facial geometry. where the coordination environment around thallium can be described as a distorted trigonal prism.

Place, publisher, year, edition, pages
2002. Vol. 331, 224-231 p.
Keyword [en]
crystal structured, thallium complexes, polydentate amine complexes, nuclear magnetic-resonance, cyanide complexes, aqueous-solutions, crystal-structure, chemical-shift, nmr, equilibrium, bromide
Identifiers
URN: urn:nbn:se:kth:diva-21488ISI: 000175179700031OAI: oai:DiVA.org:kth-21488DiVA: diva2:340186
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

Open Access in DiVA

No full text

Search in DiVA

By author/editor
Glaser, Julius
By organisation
Chemistry
In the same journal
Inorganica Chimica Acta

Search outside of DiVA

GoogleGoogle Scholar

urn-nbn

Altmetric score

urn-nbn
Total: 41 hits
CiteExportLink to record
Permanent link

Direct link
Cite
Citation style
  • apa
  • harvard1
  • ieee
  • modern-language-association-8th-edition
  • vancouver
  • Other style
More styles
Language
  • de-DE
  • en-GB
  • en-US
  • fi-FI
  • nn-NO
  • nn-NB
  • sv-SE
  • Other locale
More languages
Output format
  • html
  • text
  • asciidoc
  • rtf