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Novel monomeric phenanthroline-thallium(III) complexes multinuclear NMR characterization in organic solvents
KTH, Superseded Departments, Chemistry.
2002 (English)In: Chinese Chemical Letters, ISSN 1001-8417, E-ISSN 1878-5964, Vol. 13, no 7, p. 695-698Article in journal (Refereed) Published
Abstract [en]

A novel complex of monomeric thallium(III) with the nitrogen donor ligand phenanthroline (phen) has been prepared and characterized by multinuclear NMR (H-1, C-13, Tl-205). The three complexes exist in equilibria in DMSO and acetonitrile solution which was proved by the Tl-205 NMR spectra. The H-1 and C-13 NMR spectra of tris-phen Tl(III) complex have been measured, where the spin-spin coupling between Tl (I = 1/2) and C-13 or H-1 signals were observed with the H-1 and C-13 NMR spectroscopy in acetonitrile. The coupling constants are presented and the chemical shifts of complexes are discussed in detail.

Place, publisher, year, edition, pages
2002. Vol. 13, no 7, p. 695-698
Keyword [en]
thallium(III), phenanthroline (phen), N-donor ligands, NMR spectroscopy, aqueous-solution
Identifiers
URN: urn:nbn:se:kth:diva-21714ISI: 000176817000034OAI: oai:DiVA.org:kth-21714DiVA, id: diva2:340412
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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