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Asymmetric reduction of azirines; a new route to chiral aziridines
KTH, Superseded Departments, Chemistry.
2002 (English)In: Chemical Communications, ISSN 1359-7345, E-ISSN 1364-548X, no 16, 1752-1753 p.Article in journal (Refereed) Published
Abstract [en]

The first enantioselective reduction of aromatic 2H-azirines yields aziridines in up to 70% ee, using the aminoalcohol[RuCl2(p-cymene)](2) catalyzed asymmetric transfer hydrogenation reaction.

Place, publisher, year, edition, pages
2002. no 16, 1752-1753 p.
Keyword [en]
transfer hydrogenation, alkene aziridination, carbonyl-compounds, ketones, catalysts, complexes, ligand, enantioselectivity, mechanism, alcohols
Identifiers
URN: urn:nbn:se:kth:diva-21827DOI: 10.1039/b203932jISI: 000177492600048OAI: oai:DiVA.org:kth-21827DiVA: diva2:340525
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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