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Thermochemical properties of alpha-hydroxy-alkoxyl radicals in aqueous solution
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2002 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 106, no 46, 11127-11129 p.Article in journal (Refereed) Published
Abstract [en]

Experimental kinetic data related to the reaction of carbonyl compounds with peroxynitrite anion, ONOO-, in aqueous solutions was combined with estimated rate constants for the recombination of alkoxyl radicals with nitrogen dioxide. The equilibrium constants for O- transfer from ONOO- and OH transfer from ONOOH to the carbonyls were derived and the Gibbs' energies of formation of the neutral and anionic alpha-hydroxy alkoxyl radicals were calculated. By means of these data the O-H bond strengths in carbonyl hydrates as well as reduction potentials of the alkoxyl radicals were obtained.

Place, publisher, year, edition, pages
2002. Vol. 106, no 46, 11127-11129 p.
Keyword [en]
peroxynitrous acid, one-electron, water
Identifiers
URN: urn:nbn:se:kth:diva-22059DOI: 10.1021/jp021478nISI: 000179336100022OAI: oai:DiVA.org:kth-22059DiVA: diva2:340757
Note
QC 20100525Available from: 2010-08-10 Created: 2010-08-10 Last updated: 2017-12-12Bibliographically approved

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