Change search
ReferencesLink to record
Permanent link

Direct link
Thermochemical properties of alpha-hydroxy-alkoxyl radicals in aqueous solution
KTH, Superseded Departments, Chemistry.
KTH, Superseded Departments, Chemistry.
2002 (English)In: Journal of Physical Chemistry A, ISSN 1089-5639, E-ISSN 1520-5215, Vol. 106, no 46, 11127-11129 p.Article in journal (Refereed) Published
Abstract [en]

Experimental kinetic data related to the reaction of carbonyl compounds with peroxynitrite anion, ONOO-, in aqueous solutions was combined with estimated rate constants for the recombination of alkoxyl radicals with nitrogen dioxide. The equilibrium constants for O- transfer from ONOO- and OH transfer from ONOOH to the carbonyls were derived and the Gibbs' energies of formation of the neutral and anionic alpha-hydroxy alkoxyl radicals were calculated. By means of these data the O-H bond strengths in carbonyl hydrates as well as reduction potentials of the alkoxyl radicals were obtained.

Place, publisher, year, edition, pages
2002. Vol. 106, no 46, 11127-11129 p.
Keyword [en]
peroxynitrous acid, one-electron, water
URN: urn:nbn:se:kth:diva-22059DOI: 10.1021/jp021478nISI: 000179336100022OAI: diva2:340757
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

Open Access in DiVA

No full text

Other links

Publisher's full text

Search in DiVA

By author/editor
Merenyi, GaborLind, Johan
By organisation
In the same journal
Journal of Physical Chemistry A

Search outside of DiVA

GoogleGoogle Scholar
The number of downloads is the sum of all downloads of full texts. It may include eg previous versions that are now no longer available

Altmetric score

Total: 22 hits
ReferencesLink to record
Permanent link

Direct link