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Synthesis of an amino-functionalized model of the Fe-only hydrogenase active site
2003 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 9, no 2, 557-560 p.Article in journal (Refereed) Published
Abstract [en]

A dinuclear 2Fe2S mimic 6 of the active site of the Fe-only hydrogenases has been synthesized. Complex 6 contains a free amino group which enables linkage to a protein backbone or to a redox active species for the study of electron transfer processes in proteins or in supramolecular systems. The structures of the complex 6 and its Boc-protected precursor 5 could be verified by X-ray crystallography.

Place, publisher, year, edition, pages
2003. Vol. 9, no 2, 557-560 p.
Keyword [en]
bioinorganic chemistry, biomimetic synthesis, iron carbonyl sulfides, iron-only hydrogenase, desulfovibrio-desulfuricans, iron hydrogenase, chemistry, acid, coordination, mechanism
URN: urn:nbn:se:kth:diva-22203ISI: 000180592000021OAI: diva2:340901
QC 20100525Available from: 2010-08-10 Created: 2010-08-10Bibliographically approved

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