Synthesis of an amino-functionalized model of the Fe-only hydrogenase active site
2003 (English)In: Chemistry - A European Journal, ISSN 0947-6539, E-ISSN 1521-3765, Vol. 9, no 2, 557-560 p.Article in journal (Refereed) Published
A dinuclear 2Fe2S mimic 6 of the active site of the Fe-only hydrogenases has been synthesized. Complex 6 contains a free amino group which enables linkage to a protein backbone or to a redox active species for the study of electron transfer processes in proteins or in supramolecular systems. The structures of the complex 6 and its Boc-protected precursor 5 could be verified by X-ray crystallography.
Place, publisher, year, edition, pages
2003. Vol. 9, no 2, 557-560 p.
bioinorganic chemistry, biomimetic synthesis, iron carbonyl sulfides, iron-only hydrogenase, desulfovibrio-desulfuricans, iron hydrogenase, chemistry, acid, coordination, mechanism
IdentifiersURN: urn:nbn:se:kth:diva-22203ISI: 000180592000021OAI: oai:DiVA.org:kth-22203DiVA: diva2:340901
QC 201005252010-08-102010-08-10Bibliographically approved