Formation and structure of novel ternary complexes of thallium(III)cyanide-amine (ethylenediamine and triethylenetetramine) in solution and in solid
2003 (English)In: Inorganica Chimica Acta, ISSN 0020-1693, E-ISSN 1873-3255, Vol. 344, 117-122 p.Article in journal (Refereed) Published
A novel ternary Tl(III) complex [Tl(en)(2)(CN)](2+) has been synthesized and characterized in solution by NMR and in solid by Raman spectroscopy. This complex has been prepared in the solid state, [Tl(en)(2)(CN)](ClO4)(2) (1), and the related [Tl(tren)(CN)(2)](ClO4) (2), and their crystal structures determined by X-ray diffraction. A linear cyano-bridged supramolecular complex exists in [Tl(en)(2)(CN)](ClO4)(2). In [Tl(tren)(CN)(2)](ClO4), the thallium ion exists in a distorted octahedral geometry cis coordinated cyanides.
Place, publisher, year, edition, pages
2003. Vol. 344, 117-122 p.
thallium, cyano bridge, ethylenediamine, triethylenetetramine, multinuclear NMR, ternary complexes, nuclear magnetic-resonance, aqueous-solution, cyanide complexes, tl-205 nmr
IdentifiersURN: urn:nbn:se:kth:diva-22238ISI: 000180948100015OAI: oai:DiVA.org:kth-22238DiVA: diva2:340936
QC 201005252010-08-102010-08-10Bibliographically approved